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Solved Questions on Isomers Molecules - Exam 3 | CHEM 1120, Exams of Chemistry

Material Type: Exam; Class: General Chemistry II; Subject: Chemistry; University: Roane State Community College; Term: Spring 2005;

Typology: Exams

Pre 2010

Uploaded on 08/18/2009

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CHEM 1120 test 3 - Spring 2005 Page 1
Circle the correct answer on the answer sheet.
R = 8.314 J mol
-1
K
-1
ln(2) = 0.693
1. Which of the following molecules has stereo (optical) isomers?
a. b.
c. d. e.
2. Which of the diagrams above (question 1) has a cis-trans isomer? (a.,b.,c.,d. or e.?)
3. What is the product for the following reaction?
CH
3
CH
2
OH + C
6
H
5
COOH
presence of sulfuric acid
> ?
a. an ether b. an amide c. an ester d. a Nylon® e. a Teflon®
4. What is the product for the following reaction?
CH
2
=CH
2
+ Br
2
! ?
a. b. c. d. e.
5. The rate constant for a reaction is 1.2 × 10
-2
s
-1
at room temperature (25EC). The activation
energy is 35.0 kJ mol
-1
. What is the reaction rate constant at 100EC?
a. 7.0 × 10
54
b. 2.1 × 10
-1
s
-1
c. 7.0 × 10
-4
d. 0.998 e. 1.002
pf3
pf4
pf5

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Circle the correct answer on the answer sheet. R = 8.314 J mol-1^ K-1^ ln(2) = 0.

  1. Which of the following molecules has stereo (optical) isomers? a. b.

c. d. e.

  1. Which of the diagrams above (question 1) has a cis-trans isomer? (a.,b.,c.,d. or e.?)
  2. What is the product for the following reaction? CH 3 CH 2 OH + C 6 H 5 COOH presence of sulfuric acid^ >? a. an ether b. an amide c. an ester d. a Nylon® e. a Teflon®
  3. What is the product for the following reaction? CH 2 =CH 2 + Br 2!?

a. b. c. d. e.

  1. The rate constant for a reaction is 1.2 × 10-2^ s-1^ at room temperature (25EC). The activation energy is 35.0 kJ mol-1. What is the reaction rate constant at 100EC? a. 7.0 × 10^54 b. 2.1 × 10-1^ s-1^ c. 7.0 × 10-4^ d. 0.998 e. 1.
  1. What is the product for the following reaction? CH 3 CH 2 =CH 2 + KMnO 4!?

a. b. c. d. e.

  1. The following data was determined in a kinetics experiment. time /min pressure /atm time /min pressure /atm 0.00 2.500 4.00 0. 2.00 0.920 6.00 0.

What is the order of this reaction? a. 0 th^ b. ½ order c. 1 st^ d. 2 nd^ e. 3 rd

  1. The following initial rates were determined for one of the reactant in a reaction.

CM /M rate /M s-1^ CM /M rate /M s- 10 1.50 20 6. 15 3.78 25 9.

What is the order of the reaction? a. -1st^ b. 0 th^ c. 1 st^ d. 2 nd^ e. 3 rd

  1. The half life of a nuclear decay is 15.5 yr. After how many years will there be just 15 % left? a. 42.4 yr b. 13.0 yr c. 31.0 yr d. 95.0 yr e. 67.0 yr
  1. What is the monomer for latex (and rubber) a. b.

c. d. e.

  1. What is the name of the following compound?

a. 2,2,4-trimethylpentane b. 2,2,4-trimethyloctane c. cyclopentane d. isononane e. n-octane

  1. What functional group(s) does the compound have?

a. an amino, an alcohol group and a carboxylic acid group b. a carboxylic acid group c. an amide group and an alcohol group d. a secondary amino group and an aldehyde group e. an amino and a carboxylic acid group

  1. What is the result of the reaction: CH 3 CH 2 OH presence of sulfuric acid^ >? a. an inorganic ester b. a cyclic hydrocarbon c. an ether d. an organic ester e. TNT
  1. The slope of the plot of ln(k) versus 1/T (an Arrhenius plot) is –2.55 × 10^3 K. What is the value for the activation energy? a. 10 kJ mol-1^ b. 21.2 kJ mol-^ c. 25 kJ mol-11^ d. 46 kJ mol-1^ e. 50 kJ mol-
  2. The following data are the amounts of reactants with respect to time for a first order reaction. What is the rate constant? time /min reactant /g time /min reactant /g 0 16.520 30.0 0. 10.0 6.389 40.0 0. 20.0 2.471 50.0 0. a. 0.095 s-1^ b. 0.22 s-1^ c. 20.0 s-1^ d. 2.0 × 10-2^ s-1^ e. 1.0 × 10-3^ s-
  3. In the reaction: 2NO 2 !N 2 O 4 the mechanism is postulated to be: NO 2! NO + O slow NO + NO 2! N 2 O 3 fast N 2 O 3 + NO 2! N 2 O 4 + NO fast N 2 O 3 + O! N 2 O 4 fast The observed rate for this mechanism should be:

a. rate =kPN O 2 3

b. rate =kPNO 2

c. rate =kP N O 2 3 PNO PNO−^12

d. rate^ =kP NO^22

e. rate =kPNO PNO 2 d

  1. The organic chemist rule of thumb depends upon most organic reaction having an activation energy of about 50 kJ mol-1. If this worked, about how much faster would a reaction go if one were to increase the temperature by 10EC starting at room temperature (25EC)? a. half as fast b. 50 % faster (1.5 times faster) c. 2 times faster d. 3 times faster e. 4 times faster

KEY

1.d 2.c 3.c 4.d 5.b 6.a 7.c 8.d 9.a 10.e 11.b 12.a 13.e 14.a 15.e 16.c 17.b 18.a 19.b 20.c