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Problem Session #5 Answers for CHE100: Chemistry Calculations, Assignments of Chemistry

The answers to problem session #5 for the che100: chemistry course. It includes calculations and conversions between mass, volume, moles, temperature, and pressure for various chemical reactions.

Typology: Assignments

Pre 2010

Uploaded on 08/09/2009

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CHE100
Problem Session #5 - Answers
Instructor: Sherman Henzel
1.
20.0 mol C H x 16 mol CO
2 mol C H = 1.60 x 10 mol CO
818
2
818
2
2
2.
2.500 kg C H x 10 g
kg x 1 mol C H
114.232 g C H x 25 O
2 mol C H x 31.9988 g O
1 mol O = 8754 g O
818
3
818
818
2
818
2
2
2
3.
500.25 g C H x 1 mol C H
114.232 g C H x 18 H O
2 mol C H x 18.015 g H O
1 mol H O = 710.03 g H O
818
818
818
2
818
2
2
2
4.
7.50 x 10 O molecules x 1 mol O
6.02 x 10 O molecules x 16 mol CO
mol O x 44.010 g CO
1 mol CO = 3.51 x 10 g CO
30
2
2
23
2
2
2
2
2
8
2
25
5.
5.00 kg HCl x 1 kmol HCl
36.46 kg HCl x 2 kmol CoCl
6 kmol HCl x 165.292 kg CoCl
1 kmol CoCl = 7.56 kg CoCl
%yield = 5.75 kg
7.56 kg x 100 = 76.1 %
33
3
3
6. gas - widely separated particles; no definite volume, no definite shape; very low density
liquid - particles in contact with one another, but free to within the volume of the liquid;
definite volume; no definite shape; low density
solid - particles are in close contact; definite volume; definite shape; high density
7.
1.25 kg Cu x 10 g
kg x 205 J
g Cu = 2.56 x 10 J
3
5
8.
575.0 g C H x 394 J
g = 2.27 x 10 J
66
5
9.
1.75 x 10 J
25.0 g = 70.0 J
g
3
pf3
pf4

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Download Problem Session #5 Answers for CHE100: Chemistry Calculations and more Assignments Chemistry in PDF only on Docsity!

CHE

Problem Session #5 - Answers

Instructor: Sherman Henzel

1. 20.0 mol C H x

16 mol CO

2 mol C H

8 18 = 1.60 x 10^ mol CO

2 8 18

2 2

2.500 kg C H x

10 g kg

x

1 mol C H 114.232 g C H

x

25 O

2 mol C H

x

31.9988 g O 1 mol O 8 18 = 8754 g O

3 8 18 8 18

2 8 18

2 2

2

500.25 g C H x

1 mol C H

114.232 g C H

x

18 H O

2 mol C H

x

18.015 g H O

1 mol H O

8 18 8 18 = 710.03 g H O

8 18

2 8 18

2 2

2

7.50 x 10 O molecules x 1 mol O 6.02 x 10 O molecules x

16 mol CO mol O x

44.010 g CO 1 mol CO

(^302232) = 3.51 x 10 g CO 2

2 2

2 2

8 25 2

5.00 kg HCl x

1 kmol HCl

36.46 kg HCl

x

2 kmol CoCl

6 kmol HCl

x

165.292 kg CoCl

1 kmol CoCl

= 7.56 kg CoCl

%yield =

5.75 kg

7.56 kg

x 100 = 76.1 %

3 3 3

3

  1. gas - widely separated particles; no definite volume, no definite shape; very low density liquid - particles in contact with one another, but free to within the volume of the liquid; definite volume; no definite shape; low density solid - particles are in close contact; definite volume; definite shape; high density

7. 1.25 kg Cu x

10 g

kg

x

205 J

g Cu

= 2.56 x 10 J

3 5

8. 575.0 g C H x

394 J

g

6 6 = 2.27 x 10^5 J

1.75 x 10 J

25.0 g

J

g

3

125.0 g x

2.1 J

g C

x (0.0 - (-15.0)) C + 125.0 g x

334 J

g

  • 125.0 g x

4.18 J

g C

(100.0 - 0.0) C

  • 125.0 g x

2260 J

g

  • 125.0 g x

2.0 J

g C

x (110.0 - 100.0) C

= 3937.5 J + 41750.0 J + 52250.0 J + 282500.0 J + 2500.0 J = 382937.5 J = 3.83 x 10 J

0

0 0

0

0

0

5

(a) 29.83 in Hg x (^) 29.92 in Hg1 atm = 0.9970 atm; (b) 29.83 in Hg x (^) 29.92 in Hg 1 atm x 14.68 psi1 atm = 14.64 psi

(c) 29.83 in Hg x (^) 29.92 in Hg 1 atm x 760 mmHg1 atm = 757.7 mmHg; (d) 29.83 in Hg x (^) 29.92 in Hg 1 atm x 1.013 x 101 atm Pa = 1.010 x 10 Pa

(^55)

  1. P 1 = 1.250 atm P 2 = 655.0 mmHg V 1 = 3.500 L V 2 =?

P V = P V ; V =

P V

P

1.250 atm x 3.500 L

655.0 mmHg x

1 atm

760 mmHg

1 1 2 2 2 = 5.076 L

1 1 2

  1. P 1 = 505.0 mmHg P 2 =? V 1 = 5.00 L V 2 = 1750.0 mL

P V = P V ; P =

P V

V

505.0 mmHg x 5.00 L

1750.0 mL x

10 L

mL

1 1 2 2 2 1 1 = 1443 mmHg

2

  1. V 1 = 125.0 mL V 2 = 151.9 mL T 2 = 23.0 0 C = 296.2 K T 2 =?

V

T

V

T

; T =

V T

V

151.9 mL x 296.2 K

125.0 mL

1 = 359.9 K

1

2 2

2

2 1 1

  1. V 1 = 325.0 mL V 2 =? T 2 = 21.0 0 C = 294.2 K T 2 = -18.0 0 C = 255.2 K

V

T

V

T

; V =

V T

T

325.0 mL x 255.2 K

294.2 K

= 281.9 mL

1 2 2

1 2

23. 125.0 mL UF x

10 L

mL

x

1 mol UF

22.4 L UF

x

352.0193 g UF

1 mol UF

6 = 1.964 g UF

  • 6 6

6 6

6

352.0193 g UF

22.4 L

g

L

6

25. T = 56.3 0 C + 273.15 = 329.5 K; V = 0.5750 L

PV = nRT; P =

nRT

V

5.75 mol x 0.

L atm

mol K

x 329.5 K

0.5750 L

= 270.4 atm

  1. T = 50.0 0 C + 273.15 = 323.2 K; P = 645.0 mmHg x (1atm/760 mmHg) = 0.8487 atm

PV =

m MM

RT; MM =

mRT PV

4.350 g x 0.

L atm mol K

x 323.2 K

0.8487 atm x 1.115 L

g mol

15.00 g KClO x

1 mol KClO

122.549 g KClO

x

3 mol O

2 mol KClO

= 0.1836 mol O

PV = nRT; V =

nRT

P

0.1836 mol x 0.

L atm

mol K

x 273.15 K

1.00 atm

= 4.115 L

3

3 3

2 3

2

PV = nRT; n =

PV

RT

756.0 mmHg x

1 atm

760 mmHg

x 5.750 L

L atm

mol K

x 308.2 K

= 0.2262 mol CO

0.2262 mol CO x

2 mol C H N O

12 mol CO

x

215.087 g C H N O

1 mol C H N O

= 8.108 g C H N O

2

2

2 5 3 9 2 5 3 9 2 5 3 9