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Practice Exam 2 - General Chemistry I | CHEM 1110, Exams of Chemistry

Material Type: Exam; Professor: Condon; Class: General Chemistry I; Subject: Chemistry; University: Roane State Community College; Term: Fall 2004;

Typology: Exams

Pre 2010

Uploaded on 08/18/2009

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CHEM 1110 - Test 2 - Fall 2004 Page 1
Circle your selection of the correct answer on the answer sheet provided.
Some useful information:
( )
P
an
VV bn nRT
+
=
2
2
v
v
m
m
1
2
2
1
=
N
A
= 6.022 × 10
23
mol
-1
R = 0.08206 L atm K
-1
mol
-1
V
STP
= 22.4 L mol
-1
T/K = t
°C
/°C + 273.15
Temperature in °C versus Water Vapor Pressure in torr
0°C 4.6 torr 10°C 9.2 torr 20°C 17.5 torr
1°C 4.9 torr 11°C 9.8 torr 21°C 18.7 torr
2°C 5.3 torr 12°C 10.5 torr 22°C 19.8 torr
3°C 5.7 torr 13°C 11.2 torr 23°C 21.1 torr
4°C 6.1 torr 14°C 12.0 torr 24°C 22.4 torr
5°C 6.5 torr 15°C 12.8 torr 25°C 23.8 torr
6°C 7.0 torr 16°C 13.6 torr 26°C 25.2 torr
7°C 7.5 torr 17°C 14.5 torr 27°C 26.7 torr
8°C 8.0 torr 18°C 15.5 torr 28°C 28.3 torr
9°C 8.6 torr 19°C 16.5 torr 29°C 30.0 torr
1) Calculate the pressure of CO
2
produced from the following reaction if 10.0 atm of C
2
H
4
is
reacted with sufficient O
2
at 500°C in a closed volume and the resultant temperature is
750°C. C
2
H
4
+ 3O
2
!
2CO
2
+ 2H
2
O
A 15.0 atm B 30.0 atm C 26.5 atm D 13.3 atm E 6.63 atm
2) Calculate the volume of NH
3
produced at 300°C and 0.145 atm from the reaction of 350 g of
H
2
with an excess of N
2
according to the reaction:
N
2
+ 3H
2
!
2NH
3
A 4.05 × 10
3
L B 1.13 × 10
5
L C 8.11 × 10
3
L D 3.75 × 10
4
L E 5.63 × 10
4
L
3) An ideal gas is contained in a variable volume container. Initially the volume is 25.0 qt at
850 torr and 35°C. The temperature is raised to 200°C and the pressure adjusted to 1200 torr
by adjusting the volume. What volume was the container adjusted to?
A 50.5 qt. B 27.2 qt. C 11.5 qt. D 101 qt. E 3.10 qt.
pf3
pf4
pf5

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Download Practice Exam 2 - General Chemistry I | CHEM 1110 and more Exams Chemistry in PDF only on Docsity!

Circle your selection of the correct answer on the answer sheet provided.

Some useful information: P (^ )

an

V

+ V bn nRT

2 2

v

v

m

m

1 2

2 1

NA = 6.022 × 10^23 mol-1^ R = 0.08206 L atm K-1^ mol- VSTP = 22.4 L mol-1^ T/K = t°C/°C + 273. Temperature in °C versus Water Vapor Pressure in torr 0°C 4.6 torr 10°C 9.2 torr 20°C 17.5 torr 1°C 4.9 torr 11°C 9.8 torr 21°C 18.7 torr 2°C 5.3 torr 12°C 10.5 torr 22°C 19.8 torr 3°C 5.7 torr 13°C 11.2 torr 23°C 21.1 torr 4°C 6.1 torr 14°C 12.0 torr 24°C 22.4 torr 5°C 6.5 torr 15°C 12.8 torr 25°C 23.8 torr 6°C 7.0 torr 16°C 13.6 torr 26°C 25.2 torr 7°C 7.5 torr 17°C 14.5 torr 27°C 26.7 torr 8°C 8.0 torr 18°C 15.5 torr 28°C 28.3 torr 9°C 8.6 torr 19°C 16.5 torr 29°C 30.0 torr

  1. Calculate the pressure of CO 2 produced from the following reaction if 10.0 atm of C 2 H 4 is reacted with sufficient O 2 at 500°C in a closed volume and the resultant temperature is 750°C. C 2 H 4 + 3O 2! 2CO 2 + 2H 2 O

A 15.0 atm B 30.0 atm C 26.5 atm D 13.3 atm E 6.63 atm

  1. Calculate the volume of NH 3 produced at 300°C and 0.145 atm from the reaction of 350 g of H 2 with an excess of N 2 according to the reaction: N 2 + 3H 2! 2NH 3

A 4.05 × 10^3 L B 1.13 × 10^5 L C 8.11 × 10^3 L D 3.75 × 10^4 L E 5.63 × 10^4 L

  1. An ideal gas is contained in a variable volume container. Initially the volume is 25.0 qt at 850 torr and 35°C. The temperature is raised to 200°C and the pressure adjusted to 1200 torr by adjusting the volume. What volume was the container adjusted to?

A 50.5 qt. B 27.2 qt. C 11.5 qt. D 101 qt. E 3.10 qt.

  1. If oxygen is collected over water at a barometric pressure of 753.2 torr at 25°C, what is the pressure of the dry oxygen?

A 729.4 torr B 777.0 torr C 728.2 torr D 778.2 torr E 753.2 torr

  1. The basic assumption that is required to derive Graham’s law is:

A the number of moles add and ideal gas law is valid for each gas individually. B molecules in an ideal gas are extremely small compare to the space between molecules. C the interactions between molecules are small and can be ignored. D molecules of gasses at the same temperature have the same average kinetic energy. E vapor pressures of liquids are independent of the other gasses present.

  1. What is the ratio of the effusion rate of SF 6 compared to SCl 6?

A 1.10 B 1.29 C 0.596 D 0.772 E 1.

  1. At 10.0 atm and 100°C, acetone (propanone) is not well described by the ideal gas law. Using the van der Waal equation, calculate the pressure for of 1.96 mole of acetone contained in a volume of 6.00 L and 100°C. (a = 13.91atm L^2 mol-2^ and b = 0.0994 L mol-1)

A 12.5 atm B 10.0 atm C 11.8 atm D 7.50 atm E 8.85 atm

  1. Which of the following series indicates the correct electronegativity trend

A I > Br > Cl > F B I > Cl > Br > F C F > Br > Cl > I D F > Cl > Br > I E Cl > F > Br > I

  1. The ionization energy of P is greater than that of S. The reason for this is that:

A on this diagonal direction it is not possible to predict the overall trend. B the S atom is a larger atom than P atom and therefore has a lower ionization energy. C S atom is a smaller atom than P atom and therefore has a lower ionization energy. D this follows the general periodic trend. E this is an exception to the general trend due to the extra stability of the half filled p.

  1. Which of the following has more than 8 electrons in the Lewis dot structure about the central atom?

A CF 4 B I 3 –^ C HNO 3 D CH 2 O E SO 4 2--

  1. Which of the following has a resonance structure in the Lewis dot representation?

A H 2 SO 3 B HCl C CH 2 O D SF 6 E CO 3 2--

  1. Which of the following has a double bond in the Lewis dot structure?

A CF 4 B I 3 --^ C SF 6 D CH 2 O E SO 4 2–

  1. What is the ratio of the diffusion rate of 235 UF 6 compared to 238 UF 6?

A 1.0085 B 0.9957 C 1.0173 D 1.0042 E 0.

  1. Which of the following has two unshared pair about the central atom?

A H 2 O B SF 6 C NH 3 D SO 2 E CH 4

ANSWER SHEET

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