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Chemistry Exam - Fall 2002 (CHEM 1110) - Prof. James B. Condon, Exams of Chemistry

Questions from a chemistry exam held in fall 2002 for chem 1110 class. The exam covers various topics such as balancing chemical equations, calculating mass of products, electron configuration, quantum numbers, atomic size, ionization energy, and summarizing chemical principles.

Typology: Exams

Pre 2010

Uploaded on 08/17/2009

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CHEM 1110 test 2 - fall 2002 Page 1
CHEM 1110 test 2 - Dr. Condon’s sections - fall 2002
Do not write on this test. Use the answer sheet to indicate your answer.
1. For the following reaction, calculate the mass of KCl produced from 53.2 g of KClO
3
2KClO
3
!2KCl + 3O
2
a. 16.2 g b. 12.5 g c. 87.4 g d. 21.5 g e. 32.4 g
2. Which of the following is the electron configuration for chromium, Cr?
a. [Ar] 4s
2
, 3p
4
b. [Kr] 4s
2
, 3d
4
c. [Kr] 3d
6
d. [Ar] 4s
2
, 3d
4
e. [Ar] 3d
6
3. Which of the following are quantum numbers for an electron in an atom which are allowed
by the selection rules?
a. n = 1 , l = 1, m
l
= 0, m
s
= +½
b. n = 2 , l = 1, m
l
= 0, m
s
= +½
c. n = 2 , l = -1, m
l
= 0, m
s
= -½
d. n = 2 , l = 0, m
l
= -1, m
s
= +½
e. n = 2 , l = 0, m
l
= 0, m
s
= +1
4. Which of the following arrangement of atomic size (radius) from large to small?
Large on Left ------------> Small on Right
a. O, N, Mg, Al
b. Mg, Al, O, N
c. Mg, Al, N, O
d. O, N, Al, Mg
e. Al, Mg, N, O
5. Calculate the mass of AgCl that could be precipitated (formed) when a solution containing
7.00 g of NaCl is reacted with a solution containing 4.00 g of AgNO
3
.
AgNO
3
+ NaCl !AgCl + NaNO
3
a. 0.0235 g b. 8.25 g c. 3.38 g d. 17.2 g e. 2.00 g
pf3
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CHEM 1110 test 2 - Dr. Condon’s sections - fall 2002 Do not write on this test. Use the answer sheet to indicate your answer.

  1. For the following reaction, calculate the mass of KCl produced from 53.2 g of KClO 3 2KClO 3 !2KCl + 3O 2

a. 16.2 g b. 12.5 g c. 87.4 g d. 21.5 g e. 32.4 g

  1. Which of the following is the electron configuration for chromium, Cr?

a. [Ar] 4s^2 , 3p^4 b. [Kr] 4s^2 , 3d^4 c. [Kr] 3d^6 d. [Ar] 4s^2 , 3d^4 e. [Ar] 3d^6

  1. Which of the following are quantum numbers for an electron in an atom which are allowed by the selection rules?

a. n = 1 , l = 1, ml = 0, ms = +½ b. n = 2 , l = 1, ml = 0, ms = +½ c. n = 2 , l = -1, ml = 0, ms = -½ d. n = 2 , l = 0, ml = -1, ms = +½ e. n = 2 , l = 0, ml = 0, ms = +

  1. Which of the following arrangement of atomic size (radius) from large to small? Large on Left ------------> Small on Right

a. O, N, Mg, Al b. Mg, Al, O, N c. Mg, Al, N, O d. O, N, Al, Mg e. Al, Mg, N, O

  1. Calculate the mass of AgCl that could be precipitated (formed) when a solution containing 7.00 g of NaCl is reacted with a solution containing 4.00 g of AgNO 3. AgNO 3 + NaCl !AgCl + NaNO 3

a. 0.0235 g b. 8.25 g c. 3.38 g d. 17.2 g e. 2.00 g

  1. Phosphorous, P, has a higher ionization energy than sulfur, S. The reason for this is:

a. P has a half filled p which is favored in this case over the p^4 configuration. b. This follows the general trend for the periodic chart. c. P has fewer electrons so they are easier to remove than those for S. d. S is a smaller atom than P. e. The electron affinities compensate for this trend.

  1. Which of the following summarizes the Pauli exclusion principle?

a. Electrons should singly fulfill ml before a switch to a different value of ms. b. The half filled p is an especially stable electron configuration. c. The most stable electron configuration is the noble gas (filled p) configuration. d. No two electrons may have the same set of quantum numbers. e. Electron affinities decrease across the periodic chart to fluorine.

  1. Which of the following summarizes Hund’s rule?

a. Electrons should singly fulfill ml before a switch to a different value of ms. b. The half filled p is an especially stable electron configuration. c. The most stable electron configuration is the noble gas (filled p) configuration. d. No two electrons may have the same set of quantum numbers. e. Electron affinities decrease across the periodic chart to fluorine.

Note: In the following reactions, no attempt has been made to present the proper balancing!

  1. What are the products for the following reaction in dry conditions? Na + O 2!?

a. Na 2 O b. NaO c. Na 2 O 2 d. Na 2 O 3 e. NaO 2

  1. What are the products for the following reaction in dry conditions? Li + O 2!?

a. Li 2 O b. LiO c. Li 2 O 2 d. Li 2 O 3 e. LiO 2

1.e

2.d

3.b

4.c

5.c

6.a

7.d

8.a

9.c

10.a

11.c

12.b

13.a

14.b