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Electrophilic Aromatic Substitution Reactions: Products and Intermediates, Assignments of Organic Chemistry

The products, starting materials, and reagents for various electrophilic aromatic substitution reactions. It also indicates major and minor products and draws resonance structures for intermediates to explain predictions. Reactions include those with alcl3, h2so4, no2, hno3, br2, febr3, and ch3cl.

Typology: Assignments

Pre 2010

Uploaded on 08/16/2009

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OMe
Cl
O
NO2
Cl
O
NO2
NO2
NO2
NO2
OMe OMe
NH2
OMe
OMe
OMe
MeO
OMe
OMe
OH
Br
Br
NO2
Chem 212
Electrophilic Aromatic Substitution 2
Provide the products, starting material or reagents (more than one step perhaps) for the following reactions. Indicate which products are major and which are
minor. Be able to draw the resonance structures for the intermediates to explain your predictions.
AlCl3
H2SO4
NO2
HNO3
H2SO4
Br2
FeBr3
NO2
CH3Cl
AlCl3
Br
AlCl3
?
OH
?
OH
Cl
?
?
?
?
?
OMe
OMe
OMe
OMe
Br2
FeBr3
H2SO4
HNO3
H2SO4
CH3Cl
AlCl3

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OMe

Cl

O

NO 2

Cl

O

NO 2

NO

NO

NO

OMe

OMe

NH 2

OMe

OMe

OMe

MeO

OMe

OMe

OH

Br

Br

NO 2

Chem 212

Electrophilic Aromatic Substitution 2

Provide the products, starting material or reagents (more than one step perhaps) for the following reactions. Indicate which products are major and which are minor. Be able to draw the resonance structures for the intermediates to explain your predictions.

AlCl (^3)

H2SO 4

NO

HNO

H2SO 4

Br FeBr (^3)

NO

CH3Cl AlCl (^3)

Br

AlCl (^3)

OH

OH

Cl

OMe

OMe

OMe

OMe

Br 2 FeBr (^3)

H2SO 4

HNO

H2SO 4

CH3Cl AlCl 3