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Lecture Notes on Chemical Bonding | CHEM 1075, Study notes of Chemistry

Material Type: Notes; Professor: Kelley; Class: Fundamentals of Chemistry; Subject: SCIENCE/Chemistry; University: NorthWest Arkansas Community College; Term: Unknown 1989;

Typology: Study notes

Pre 2010

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Chem 1075 Chapter 12 Chemical Bonding Lecture Outline
Slide 2 Chemical Bond Concept
Recall that an atom has ___________and _________________electrons.
Core electrons are found _________________ to the nucleus.
Valence electrons are found in the ________________________ s and p energy subshells.
It is ___________________ electrons that are responsible for holding two or more atoms together
in a _______________________________________.
Slide 3 Octet Rule
The _________________________ states that atoms bond in such a way so that each atom
acquires _____________ electrons in its outer shell.
There are two ways in which an atom may achieve an octet.
(a) By _____________________of electrons from one atom to another
(b) By _________________________ one or more pairs of electrons
Slide 4 Types of Bonds
Ionic Bonds are formed from the ___________________________________ of electrons between
atoms to form ________________ compounds.
Covalent Bonds are formed when two atoms __________________ electrons to form
____________________________________compounds.
Slide 5 Ionic Bonds
An ionic bond is formed by the _____________________ between
____________________ charged cations and _________________
charged anions.
This ______________________________________is similar to the
attraction between opposite poles on two magnets.
Slide 6 Ionic Bonds
The ionic bonds formed from the combination of anions and cations
are _____________________________ and result in the formation of
a rigid, ________________________ structure. The structure for
____________ ordinary table salt, is shown here.
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Chem 1075 Chapter 12 Chemical Bonding Lecture Outline

Slide 2 Chemical Bond Concept

  • Recall that an atom has ___________and _________________electrons.
  • Core electrons are found _________________ to the nucleus.
  • Valence electrons are found in the ________________________ s and p energy subshells.
  • It is ___________________ electrons that are responsible for holding two or more atoms together in a _______________________________________.

Slide 3 Octet Rule

  • The _________________________ states that atoms bond in such a way so that each atom acquires _____________ electrons in its outer shell.
  • There are two ways in which an atom may achieve an octet. (a) By _____________________of electrons from one atom to another (b) By _________________________ one or more pairs of electrons

Slide 4 Types of Bonds

  • Ionic Bonds are formed from the ___________________________________ of electrons between atoms to form ________________ compounds.
  • Covalent Bonds are formed when two atoms __________________ electrons to form ____________________________________compounds.

Slide 5 Ionic Bonds

  • An ionic bond is formed by the _____________________ between ____________________ charged cations and _________________ charged anions.
  • This ______________________________________is similar to the attraction between opposite poles on two magnets.

Slide 6 Ionic Bonds

  • The ionic bonds formed from the combination of anions and cations are _____________________________ and result in the formation of a rigid, ________________________ structure. The structure for ____________ ordinary table salt, is shown here.

Slide 7 Formation of Cations

  • _________________ are formed when an atom _____________ valence electrons to become __________________________ charged.
  • Most main group ______________ achieve a noble gas electron configuration by _____________ their valence electrons and are _________________________ with a noble gas.
  • Magnesium (Group IIA/2) loses its __________ valence electrons to become Mg2+.
  • A magnesium ion has __________ (12–2=10e-) and is isoelectronic with _________.
  • See also Ch.6 Slide 25 for discussion of Positive Ionic Charge

Slide 8 Formation of Cations

  • We can use electron dot formulas to look at the formation of ____________________.
  • Each of the metals in Period 3 form cations by losing 1, 2, or 3 electrons, respectively. Each metal atom becomes ____________________________ with the preceding noble gas, ___________.

Slide 9 Formation of Anions

  • _________________ are formed when an atom ______________electrons and becomes ________________ charged.
  • Most ___________________ achieve a noble gas electron configuration by __________________ electrons to become _________________________ with a noble gas.
  • Chlorine (Group VIIA/17) gains ________valence electron and becomes Cl–.
  • A chloride ion has 18 electrons (17 + 1 = 18 e-) and is isoelectronic with ___________________.
  • See also Ch.6 Slide 26 for discussion of Negative Ionic Charge

Slide 10 Formation of Anions

  • We can also use electron dot formulas to look at the formation of _____________________.
  • The nonmetals in Period 3 gain 1, 2, or 3 electrons, respectively to form anions. Each nonmetal ion is ___________________________with the following noble gas, ________________.
  1. CO 2 5. HCN (C is central) 6. PCl 5
  2. NO 3 1-^ 8. ClO 2 1-^ 9. Cl 2 CO (C is central)

Slide 16 Polar Covalent bonds

  • _____________________ bonds result from the __________________ of valence electrons.
  • Often, the two atoms do not share the electrons ________________. One of the atoms holds on to the electrons _______________________________ than the other.
  • When one of the atoms holds the shared electrons more tightly, the bond is __________________.
  • A __________________________________________ is one in which the electrons are ________ shared equally.

Slide 17 Electronegativity

  • Each element has an innate ______________ to ___________________valence electrons.
  • _____________________________is the ability of an atom to ____________________________ in a chemical _______________.
  • Linus Pauling devised a method for measuring the electronegativity of each of the elements.
  • Fluorine is the _________________ electronegative element.

Slide 18 Electronegativity

Slide 19 Electronegativity Differences

  • The electronegativity of H is ______ and of Cl is _______.
  • Since there is a _____________________________ in electronegativity between the two elements (___________________), the bond in H Cl is polar.
  • Since Cl is ______________ electronegative, the bonding electrons are attracted ______________ the Cl atom and _______________ from the H atom. This will give the Cl atom a _____________ ____________________ charge and the H atom a _______________________________________ charge.

Slide 20 Delta Notation for Polar bonds

  • We use the Greek letter delta, δ, to indicate a ________________ bond.
  • The ______________________ charged atom is indicated by the symbol _______, and the __________________________ charged atom is indicated by the symbol _______. This is referred to as ________________________________________ for polar bonds.

δ+ H Cl δ–

Slide 21 Delta Notation for Polar bonds

  • The hydrogen halides, HF, HCl, HBr, and HI all have _____________ _______________________ bonds.
  • The halides are all ________________ electronegative than hydrogen and are designated with a ________.

Slide 22 Nonpolar Covalent Bonds

  • What if two atoms in a covalent bond have the __________________ _______________________electronegativities?
  • The bond is__________polarized and it is a _____________________ _____________________________________. If the electronegativity difference is ___________________________, it is usually considered a _______________________bond.
  • The diatomic halogen molecules have __________________________ ____________________ bonds.