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Material Type: Assignment; Professor: Ziegler; Class: General Chemistry III; Subject: Chemistry ; University: Central Oregon Community College; Term: Unknown 1989;
Typology: Assignments
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Class period 1 - Reading pp. 668-684 (m)
Class period 2 - Reading pp. 684 (b) – 697,
Answers to problems not in the appendix. 16.16 a) HCN b) OH-^ c) H 2 PO 4 -^ d) CH 3 NH 3 + 16.82 a) Ammonia is the stronger base (larger Ka),b) the hydroxylammonium ion is the stronger acid, (the weaker the conjugate base, the stronger the conjugate acid). c) for NH 4 +^ Ka = 5.6 x 10-10^ and for hydroxylamine, the Ka = 9.1 x 10-
16.73 a)
3 2 2 3 2 2 b 3 2 2 (^3 )
(the chemical equation for K )
b^ =^ (the Kb expression)
b) 32 2 3 (^32) b 3
− − − − − −
c)
2 2 2 2 b 2
CHO H O CHO H OH
K CHO H^ OH CHO
− − − −
= ^
16.78 [OH-^ ] = 8.9 x 10-5^ MMMM Kb = 1.6 x 10- 16.76 [OH-^ ] = 2.1 x 10-3^ MMMM pH = 11.
16.86 a) acidic, b) neutral, c) basic, d) acidic e) acidic