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Key Concepts for General Chemistry III | CH 223, Assignments of Chemistry

Material Type: Assignment; Professor: Ziegler; Class: General Chemistry III; Subject: Chemistry ; University: Central Oregon Community College; Term: Unknown 1989;

Typology: Assignments

Pre 2010

Uploaded on 08/17/2009

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CH 223 – Ziegler KEY CONCEPTS
KEY CONCEPTSKEY CONCEPTS
KEY CONCEPTS Spring 08
Chapter 16 10th ed.
Class period 1 - Reading pp. 668-684 (m)
1. Given an acid-base reaction, identify the Bronsted-Lowry acids and bases and conjugate pairs.
Problem 16.17.
2. Given the formula of a Bronsted-Lowry acid or base, write the formula of its conjugate. Problem
16.15, 16.16.
3. Given any one of [H+], [OH-], pH, or pOH, calculate any of the other quantities. Problems
16.37
4. Given the [H+], [OH-], pH, or pOH of a solution, classify the solution as acidic, neutral, or
basic. Problem 16.37, again.
5. Given the concentration of a solution of strong acid or base, calculate any of [H+], [OH-], pH,
or pOH. Problems 16.43, 16.45
Class period 2 - Reading pp. 684 (b) – 697,
6. Using the Bronsted-Lowry model, write an equation to explain why a species acts as an acid.
Problem 16.19.
7. Given a weak acid, write out the dissociation equation and Ka expression. Problem 16.51 a
8. Relate Ka and pKa.
9. Relate Ka to acid strength. Problem 16.81 a, b
10. Given pH or [H+] and [HB]o, calculate Ka. Problem 16.53.
11. Given Ka and [HB]o, calculate [H+] or pH. Problem 16.57, 16.59.
12. Relate Ka and Kb. Problem 16.81c, 16.82 c
Class period 3 - Reading pp. 699 --701, and 708 (m) - 709.
13. For Bronsted-Lowry bases, substitute base concepts into:
o Key Concepts 6 and 7. Problem 16.73
o Key Concepts 8 and 9. Problem 16.82 a), b), 16.81 a), b)
o Key Concept 10. Problem 16.78
o Key Concept 11. Problem 16.76.
14. Predict whether a given salt solution is acidic, neutral, or basic. Problems 16.85, 16.86
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CH 223 – Ziegler KEY CONCEPTSKEY CONCEPTSKEY CONCEPTSKEY CONCEPTS Spring 08

Chapter 16 10 th^ ed.

Class period 1 - Reading pp. 668-684 (m)

  1. Given an acid-base reaction, identify the Bronsted-Lowry acids and bases and conjugate pairs. Problem 16.17.
  2. Given the formula of a Bronsted-Lowry acid or base, write the formula of its conjugate. Problem16.15, 16.16.
  3. Given any one of [H+], [OH-], pH, or pOH, calculate any of the other quantities. Problems16.
  4. Given the [H+], [OH-], pH, or pOH of a solution, classify the solution as acidic, neutral, orbasic. Problem 16.37, again.
  5. Given the concentration of a solution of strong acid or base, calculate any of [H+], [OH-], pH,or pOH. Problems 16.43, 16.

Class period 2 - Reading pp. 684 (b) – 697,

  1. Using the Bronsted-Lowry model, write an equation to explain why a species acts as an acid.Problem 16.19.
  2. Given a weak acid, write out the dissociation equation and Ka expression. Problem 16.51 a
  3. Relate Ka and pKa.
  4. Relate Ka to acid strength. Problem 16.81 a, b
  5. Given pH or [H+] and [HB]o, calculate Ka. Problem 16.53.
  6. Given Ka and [HB]o, calculate [H+] or pH. Problem 16.57, 16.59.
  7. Relate Ka and Kb. Problem 16.81c, 16.82 c Class period 3 - Reading pp. 699 --701, and 708 (m) - 709.
  8. For Bronsted-Lowry bases, substitute base concepts into: o o Key Concepts 6 and 7. Problem 16.73Key Concepts 8 and 9. Problem 16.82 a), b), 16.81 a), b) o Key Concept 10. Problem 16. o Key Concept 11. Problem 16.76.
  9. Predict whether a given salt solution is acidic, neutral, or basic. Problems 16.85, 16.

CH 223 – Ziegler KEY CONCEPTSKEY CONCEPTSKEY CONCEPTSKEY CONCEPTS Spring 08

Chapter 16 10 th^ ed.

Answers to problems not in the appendix. 16.16 a) HCN b) OH-^ c) H 2 PO 4 -^ d) CH 3 NH 3 + 16.82 a) Ammonia is the stronger base (larger Ka),b) the hydroxylammonium ion is the stronger acid, (the weaker the conjugate base, the stronger the conjugate acid). c) for NH 4 +^ Ka = 5.6 x 10-10^ and for hydroxylamine, the Ka = 9.1 x 10-

16.73 a)

3 2 2 3 2 2 b 3 2 2 (^3 )

(the chemical equation for K )

b^ =^ (the Kb expression)

CH NH H O CH NH OH

K CH^ NH^ OH

CH NH

b) 32 2 3 (^32) b 3

CO H O HCO OH

K HCO^ OH

CO

− − − − − −

= ^   ^ 

c)

[ ]

2 2 2 2 b 2

CHO H O CHO H OH

K CHO H^ OH CHO

− − − −

= ^   



16.78 [OH-^ ] = 8.9 x 10-5^ MMMM Kb = 1.6 x 10- 16.76 [OH-^ ] = 2.1 x 10-3^ MMMM pH = 11.

16.86 a) acidic, b) neutral, c) basic, d) acidic e) acidic