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Hybridization and Molecular Shape Material Type: Notes; Professor: Haaf; Class: Principles of Chemistry; Subject: Chemistry; University: Ithaca College; Term: Fall 2010;
Typology: Study notes
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Bonding Domains
pairs attached hybridization # non- bonding electrons (lone pairs) shape bond angles example 4 sp^3 tetrahedral 109 o
4 sp^3 pyramidal < 109o
4 sp^3 bent < 109o
3 sp^2 trigonal planar 120 o
3 sp^2 bent < 120o^ O 3 2 sp 0 linear 180 o
Bonding Domains
pairs attached hybridization # non- bonding electrons (lone pairs) shape bond angles example 6 d^2 sp^3 octahedral 90 o
6 d^2 sp^3 square pyramid <90o
6 d^2 sp^3 square planar < 90o XeF 4 5 dsp^3 trigonal bipyramid 90 o, 120o^ PCl 5 5 dsp^3 see-saw < 90o, 120 o SeF 4 5 dsp^3 t-shaped ~ 90o ClF 3 5 dsp^3 linear 180 o^ XeF 2